You won’t gain 6hp from that fuel. You will gain some power simply because it’s oxygenated, but you have to rejet and tune for oxygenated fuel. And that fuel is hard on components requiring draining and more maintenance. Maybe you are at a high elevation or something, but I don’t know why 93 wouldn’t work, or especially 100. I run 91 in my 13.5:1 builds.
There is a LOT of misinformation on fuels and what’s needed for certain motors and compressions. Lots of it is propagated by older guys that are used to old motors with iron heads and inefficient ports. You can have two motors, same CR but have totally different fuel requirements. The 450 motors are much more efficient and since they are water cooled, all aluminum, 4 valves, and a decent port layout (especially if your head was ported by a reputable shop), they can run a higher CR with lower octane than other motors. Throw in a big cam like your S3, and they are even more forgiving.
Buuuutttttt, I’m not going to tell you you will be absolutely safe with 91, 93, or even 115, that’s for you to decide and tune for. But remember, the lower the octane you can run, the more power you will make. And with trail riding, or even to a lesser extent on the track, you are generally not WOT for long periods of time where you will be getting super high temps that will cause issues. On the trail if you start lugging the engine, too low of an octane can be an issue, but since you chose to go with a S3 cam that tells me you only run at higher RPMs which is safer.
There are times that I will mix in or even run straight race gas, and that’s at the dunes. When it’s crazy hot ambient and you are working that motor extra hard in the sand and constantly at WOT you need some extra octane.