I don't know if I want to get into this but, here we go. While 1BAD was close with his description, his wording was off slightly. Excellent shot though.
Predetonation is not really a word. Pre-ignition and detonation are some things that can happen from poor fuel though. Pre-ignition is the fuel lighting off on it's own from somewhere inside the combustion chamber other than from the spark plug and obviously an unwanted scenario. This would be the same as jacking the timing around so it fires, oh, say 15-25 degrees before it is supposed to. This is usually caused by some hot spot in the combustion chamber, really low octane fuel, or just plain poor fuel. It can also sometimes be caused by lean jetting when the machine is working really hard but, this scenario lends itself more to detonation, it's a really fine line there.
Detonation is the explosion of fuel when an engine is being worked at it's maximum capacity over a long enough period of time to completely vaporize the incoming charge and then compress it enough that it explodes under the pressure of being squeezed instead of ignited by the plug and then burned in a controlled fashion. (that was a really long sentence, sorry) Too low of octane fuel will do this simply because the bond between the molecule chains aren't strong enough and the fuel vaporizes too easily. This is also the reason I don't like mixxing fuels, the molecular bonds in these chains can be broken apart by different compounds in the differing fuel types. Like mixxing pump gas and race fuel, just plain not a good idea.
The two things you should realize about detonation and pre-ignition, pre-ignition will really raise the operating temps of the motor quickly since the engine is fighting itself to run. Detonation is just self contained violence. It happens so quickly and is over so fast that unless it does permanent damage (most likely the case) you'll never know it happened until you tear the motor apart because it suddenly has become slow running. Stuck rings, bent rods, broken rods, broken piston tops, broken piston skirts, all can be the results of detonation. The giveaway is "spots" of carbon missing from the piston top or cylinder head. Pre-ignition is just that, the fuel is still burning, not exploding. With pre-ignition it is more likely to melt the dome of the piston away, most times just to the exhaust side of the spark plug tip.
When diagnosing a piston failure it's important to look at the evidence carefully. If it has a hole melted in it and also signs of detonation, what would be the actual cause? Pre-ignition! Why? Because as the piston dome melts away it spreads the metal around on the dome and as the engine fights to run it gets these particles hot and starts lighting the fuel off in different locations, in effect, causing detonation when the flame fronts colide.
I know I have explained this before a couple times on this forum, maybe we can pin this?
Sorry about that 1BAD, don't mean to step on your toes. :blush: Welcome to the site.
Tony