Aviation fuel is NOT designed to perform in a typical automotive style engine....
It will burn....yes, and yes, SOME does have more octane....but dont confuse the octane 'rating' of AvGas to your typical motor fuel..... because they are not the same....
it is true that AvGas is rated for less dense air (higher altitude).... even though 210Driver is correct, and that upon take-off (most critical area for aircraft) is performed at ground level, the AvGas constituants still develop the octane levels of this fuel to be used at a much less dense air mix than a typical auto......even a small trainer aircraft will have a ceiling of close to 10,000 ft.....80/87 or 100/110 fuel (two typical types of Avgas) are rated using different formulas than pump gas..... one of the reasons told to me by someone in the industry of chemical analysis for fuels is this....the load variations of an aircraft do not fluctuate nearly as much as a typical automobile..... even upon Take-Off.... and 210Driver can confirm this.... a typical small aircraft engine is designed to work at a specific RPM level...irregardless of power output.....some small aircraft (piper cubs and small trainers) will not have variable pitch propellers, but a typical high performance retractable geared aircraft such as a '210' or Bonanza that I owned, do. You simply set the RPM level of the engine and 'feather' or alter the pitch of the propeller to control air speed. Yes, you will push the throttle all the way in for initial take-off, but the RPMs will rarely vary more than 200-300rpms....you change the pitch of the propeller to compensate for more power vs more speed. Also, the RPM of an aircraft engine is relatively low compared to your auto.....2800rpm is about average If I remember correctly (its been while since ive flown)....whereas your typical auto will start off at 1000rpm and can race up to 6000 rpm on a typical auto.....and your going from a dead start to high speed constantly and repeatedly under a LOAD....whereas in an aircraft, you take off, you fly at a constant speed/rpm....then you land... thats it... very little variance upon the engine...
AvGas has a lot of additives to reduce heat and maintain its burn qualities, plus all the additives to help disipate WATER, a major issue with aircraft, not to mention the dyes....blue/red etc....(which are also added to some race fuels)....and additives to reduce what we call 'carburetor Icing'....the freezing of fuel along the venturi of the carb....(very bad).....but easy to control with carb heat IF you remember...

(long story)
its also a violation of law to dispense Avgas into a container (at least here in Cali)....so many airports will not allow this.....but some, if not closely regulated, really dont care.....
at any rate......yes, ive burned Avgas in my street car way back in the 70's...and yes, it ran fine....but still had stock compression 11:1....NO, Avgas will not destroy rubber or gaskets or the like....most aircraft still flying today are from the 50's/60's/70's....using typical single venturi (barrel) carbs.....after that.. many high performance aircraft went to fuel injection.... and NO, I will not burn Avgas in my R.....
anyways.....use it...dont use it.... its up to you..... jmho....Greg